Flowing atmospheric-pressure afterglow
WebMay 31, 2011 · The advent of ambient desorption/ionization mass spectrometry has resulted in a strong interest in ionization sources that are capable of direct analyte sampling and ionization. One source that has enjoyed increasing interest is the flowing atmospheric-pressure afterglow (FAPA). The FAPA has been proven capable of directly … WebAug 6, 2013 · The flowing atmospheric-pressure afterglow (FAPA) is a promising new source for atmospheric-pressure, ambient desorption/ionization mass spectrometry. However, problems exist with reproducible sample introduction into the FAPA source. To overcome this limitation, a new FAPA geometry has been developed in which concentric …
Flowing atmospheric-pressure afterglow
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WebNov 14, 2014 · A particularly promising source is the flowing atmospheric-pressure afterglow (FAPA) that has been developed within the Hieftje lab at Indiana University. In this chapter we explore the development, characterization and applications of the FAPA source. Fundamental examinations into reagent formation and optical-emission … WebFeb 1, 2024 · For instance, our group showed that a helium‑oxygen flowing atmospheric-pressure afterglow (He:O 2-FAPA) source yielded enhanced ion signals for small polar analytes, but compounds with aromatic rings underwent chemical modification to produce pyrylium species.
WebMay 4, 2024 · We describe the plasma chemistry in a helium flowing atmospheric pressure afterglow (FAPA) used for analytical spectrometry, by means of a quasi-one-dimensional (1D) plasma chemical kinetics model. We study the effect of typical impurities present in the feed gas, as well as the afterglow in ambient humid air. WebJul 27, 2024 · Here, a reactive flowing atmospheric-pressure afterglow (reactive-FAPA) AMS source is developed for rapid isomer differentiation by derivatization of analytes in real time. The effects of the reactive-FAPA operating conditions on the reagent and product ions were studied and optimized for highly volatile and non-volatile model compounds with ...
Over the years many variations of the instrument have been made. In the beginning during the 1960s there was the study of flowing afterglow plasma. This study was done by Eldon Ferguson, Art Schmeltekopf and Fred Fehsenfeld at National Bureau of Standards in Boulder, Colorado. Then in the 1970s it was flowing drift tube, flowing afterglow Langmuir probe (FALP), and variable temperature flowing afterglow Langmuir probe (VT-FLAP). With the addition of the drift tube the … WebApr 1, 2024 · The Flowing Atmospheric-Pressure Afterglow (FAPA) source is particularly attractive for portable, direct-analysis mass spectrometry due to its simple design and …
WebMar 2, 2024 · In this work, a field-switching (FS) technique is employed with a flowing atmospheric pressure afterglow (FAPA) source in drift tube ion mobility spectrometry …
Webplasma-based sources, DART, the flowing atmospheric-pres-sureafterglow(FAPA),andthelow-temperatureplasma(LTP) probe, were compared … green shippingWebJul 15, 2011 · One source that has enjoyed increasing interest is the flowing atmospheric-pressure afterglow (FAPA). The FAPA has been proven capable of directly desorbing/ionizing samples in any phase (solid, liquid, or gas) and with impressive limits of detection (<100 fmol). The FAPA was also shown to be less affected by competitive … fmr budget activityWebJul 1, 2009 · @misc{etde_21432553, title = {The flowing atmospheric-pressure afterglow. A glow discharge for molecular mass spectrometry} author = {Shelley, J T, Pfeuffer, K P, Ray, S J, and Hieftje, G M} abstractNote = {Complete text of publication follows. Recently a number of atmospheric-pressure ionization sources have emerged … fmr boston maWebApr 20, 2024 · We describe the plasma chemistry in a helium flowing atmospheric pressure afterglow (FAPA) used for analytical spectrometry, by means of a quasi-one-dimensional … green shipping conference 2023WebNov 29, 2011 · Here, the atmospheric-pressure glow discharge (APGD) and afterglow of a helium flowing atmospheric-pressure afterglow (FAPA) ionization source were examined by optical emission spectroscopy. Spatial emission profiles of species created in the APGD and afterglow were recorded under a variety of operating conditions, … fmr chapter 14WebOne such ADI-MS source, the flowing atmospheric-pressure afterglow (FAPA), is capable of direct analysis of solids just by aiming the source at the solid surface and sampling the produced ions into a mass spectrometer. However, direct introduction of significant volumes of liquid samples into this source has not been possible, as solvent … green shipping boxesWebJun 8, 2024 · Flowing atmospheric-pressure afterglow plasma gas flow rate The signal dependence on the plasma gas flow rate was also studied ( Fig. 3 b). Regarding the gas-phase analyte injection, 2,6-DTBP, there is a considerable increase (around 11 times) in signal intensity as the plasma gas flow rate rises from 100 to 300 mL min −1 , that is … fmrbwmc30311ld